Two stunning strikes from Ben Close, one in either half, helped topple the Gills from the summit of the fourth-tier table and give Rovers their third win in as many matches.
Several players caught the eye as Doncaster produced another strong team performance to get win.
Here’s our ratings.
9. Ben Close - 9
Once again the hero thanks to two stunning strikes. This is the best Rovers fans have seen of Ben Close, long may it continue. Photo: Howard Roe/AHPIX LTD
10. Louie Marsh - 7
Almost gifted Gillingham an early opener with a misplaced pass but quickly atoned to send Mo Faal through on goal. Looks a real talent on the ball, an encouraging full league debut. Photo: Howard Roe/ahpix.com
11. Mo Faal - 6
Should have opened the scoring when played through one-on-one inside the opening five minutes but forced the indirect free-kick which led to the opening goal. Photo: Howard Roe/ahpix.com
12. Joe Ironside - 6
Like Broadbent, helped Rovers regain control in the game following his introduction. Unlucky not to start. Photo: Howard Roe/AHPIX LTD